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Heres a breakdown of the vitamins typically found in a B complex supplement and their main functions: Biotin (vitamin B7) Cyanocobalamin (vitamin B12) Folic acid (vitamin B9) Niacin or niacinamide (vitamin B3) Pantothenic acid (vitamin B5) Pyridoxine (vitamin B6) Riboflavin (vitamin B2) Thiamine (vitamin B1) Common Uses of Vitamin B Complex Prevent or Treat Vitamin B Deficiencies: B complex supplements can be used to prevent or treat deficiencies caused by poor diet, certain medical conditions, or absorption issues