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The use of ditopic P,N-donor ligand that double as linkers lead to different Re(I)/Au(I) heteronuclear complexes of the type, fac -[Re-(bipy)(CO) 3 (LAuCl)] + ( ReAu-5 and ReAu-7 ) and [( fac -[Re(bipy)(CO) 3 (L)]) 2 Au] 3+ ( ReAu-6 and ReAu-8 ) with red-shifted emission profiles up to 605 nm attributed to a triplet metal-to-ligand charge transfer transition (Chart 11)

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doi: 10.1080/00480169.1998.36089

J Chromatogr A 1488:93103