kinetics of glutathione and ferricyanide reaction in aqueous media Redox glutathione disul fi de; Ellman Electrochemical sensing glutathione, nicotinamide adenine
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This acts as a reservoir and cannot cross the endothelial barrier

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Sulforaphane, a naturally occurring small molecule, activates the Nrf2-ARE pathway, upregulates antioxidant enzymes such as SOD and CAT, reduces ROS accumulation, and inhibits apoptosis

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