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It's a more meaningful decision than it first appears vial size affects cost-per-milligram, reconstitution concentration, and how much usable research window you get before reconstituted material should be discarded

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Gibbs free barrier and released energies involved in hydrogen abstraction from the different sites of glutathione by an OH radical were studied at the B3LYP/6-31G(d,p), B3LYP/AUG-cc-pVDZ, M06/AUG-cc-pVDZ, M06-2X/AUG-cc-pVDZ levels of density functional theory