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Redox signaling of angiogenesis
Direct binding of copper ions to fatty acylated components in the tricarboxylic acid (TCA) cycle results in protein aggregation and dysregulation (40), blocking the TCA cycle and inducing proteotoxic stress and cell death (Fig
This results in the stabilization of Nrf2 and the activation of its transcriptional pathway, facilitating the expression of cytoprotective genes [198]
