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By these reactions, GSH is oxidized to glutathione disulfide (GSSG)

Cruciferous vegetables contain goitrogens which may block iodine uptake in the thyroid gland in low iodine states

[DOI] [PubMed] [Google Scholar] Monks T.J., Lau S.S., Highet R.J., Gillette J.R

The science is actually quite fascinating: your skin produces melanin (the pigment that gives skin its colour), and sometimes this process goes a bit overboard, especially after sun exposure or hormonal changes