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Monitoring: Blood tests for serum 25-hydroxyvitamin D levels help guide safe dosing
& BERRY, D
C218 is located very close to the active site, E181, so insertion of a bulky sulfur carrying a negative charge would conformationally change the active site, leading to the observed loss of kinase activity (Giovinazzo et al., 2021)
The k red value of 1.4 10 6 M 1 s 1 for PfGrx C88S (SH) 2 is about two orders of magnitude higher than the highest k ox value for PfGrx C32S/C88S (SSG) in accordance with a physiological relevance of glutaredoxins as deglutathionylating enzymes
