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Metabolism: The metabolic fate of Somatotropin was not studied

327 Nonenzymatic oxidation of 13-HpOTrE into a small amount (7%) of 13-oxo-OTrE at room temperature in dichloromethane and in the presence of 5,10,15,20-tetraphenyl-21 H ,23 H -porphyrin iron(III) chloride (TPP/Fe(III)) and 2,4,6-tri- tert -butylphenol, which generate an alkoxyl anion from the hydroperoxide, has been reported by Wilcox et al., 298 whereas the formation of a small amount (1.2%) of all- trans ketones (10( E ),12( E )-9-oxo-ODE and 9( E ),11( E )-13-oxo-ODE) by photosensitized oxidation of LA-derived 9- and 13-HpODEs has been described by Neff in the presence of methylene blue at 0 C in dichloromethane (Scheme 37)

58 HaysR.WicklineL.CaganR